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  • Product Name:   Dicarbonylacetylacetonato rhodium(I)
  • Synonyms:   Dicarbonyl-(2,4-pentandione)-rhodium;Dicarbonyl(2,4-pentanedionato)rhodium;Dicarbonylacetylacetonatorhodium;Dicarbonylrhodium acetylacetonate;Rhodium dicarbonylacetylacetonate
  • CAS No.:   14874-82-9
  • Molecular Formula:   C7H7O4Rh
  • Molecular Weight :   258.03
  • Specification :   98%
  • Place of Origin:   China
  • Appearance :   
  • Document :   Download

Description of Dicarbonylacetylacetonato rhodium(I)



Dicarbonylacetylacetonato rhodium(I) Chemical Properties


Melting point  154-156 °C(lit.)


solubility  Soluble in acetone


form  Needles or Flakes


color  Greenish-red


Water Solubility  insoluble


NIST Chemistry Reference Rhodium, dicarbonyl(2,4-pentanedionato-o,o')-, (sp-4-2)-(14874-82-9)




Safety Information


Hazard Codes  Xi,F,T


Risk Statements  36/37/38-44-43-25


Safety Statements  26-37/39-45-36/37/39-24/25


RIDADR  3282


WGK Germany  3


TSCA  No


HazardClass  6.1


PackingGroup  III




Dicarbonylacetylacetonato rhodium(I) Usage And Synthesis


Reaction
  1. Precatalyst for hydroformylation of olefins.
  2. Precatalyst for silylformylation of olefins.
  3. Precatalyst for carbonylative silylcarbo-cyclization in the syntheses of isodomoic acids.
  4. Precatalyst for the conjugate addition of aryl- and alkenylboronic acids to enones.



Chemical Properties Red/Green Crystalline Powder




Dicarbonylacetylacetonato rhodium(I) Preparation Products And Raw materials


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Dicarbonylacetylacetonato rhodium(I) related products :

Rhodium (triphenylphosphine)carbonylacetylacetonate |Rhodium carbonyl chloride |Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] |BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE |(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE |Iridium |Iridium(III) chloride hydrate |Hexachloroiridic acid hexahydrate |Dipotassium hexachloroiridate |Ammonium hexachloroiridate(IV) |Chloro(1,5-cyclooctadiene)iridium(I) dimer |(Pentamethylcyclopentadienyl)iridium(III) chloride dimer |Iridium(III) acetylacetonate |1,2,3-Triaqua-1,2:1,2:1,3:1,3:2,3:2,3-hexa-m-acetato(O,O')-m3-oxo-triangulo-triiridium acetate |Ruthenium |Ruthenium(III) chloride |Ruthenium trichloride |Ruthenium(IV) oxide hydrate |Ruthenium dioxide |hexakis[mu-(acetato-O:O')]-mu3-oxo-triangulo-triruthenium acetate |Ruthenium nitrosyl nitrate |Dichloro(p-cymene)ruthenium(II) dimer |Ruthenium(II) chloride mesitylene dimer |Benzeneruthenium(II) chloride dimer |Tris(triphenylphosphine)ruthenium(II) chloride |Chloroauric acid |Acetylacetonatobis(2-phenylpyridine)iridium |Tris(2-phenylpyridine)iridium |Ir(Mppy)3 , Tris[2-(p-tolyl)pyridine]iridiuM(III) |Bis(1-phenyl-isoquinoline)(Acetylacetonato)iridium(III) |Ir(piq)3, Tris[1-phenylisoquinolinato-C2,N]iridium(III) |Firpic |Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) |(R,R)-DIPAMP |(S,S)-DIPAMP |(R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE |(S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE |9-Fluorenone |9,9-Bis(4-hydroxyphenyl)fluorene |3-Bromo-9H-fluoren-9-one |

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