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  • Product Name:   Chloro(1,5-cyclooctadiene)iridium(I) dimer
  • Synonyms:   BIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) DICHLORIDE;DI-MU-CHLOROBIS[(ETA-CYCLOOCTA-1,5-DIENE)IRIDIUM (I)];DI-MU-CHLORO-BIS[(1,2,5,6-ETA)-1,5-CYCLOOCTADIENE]DIIRIDIUM;CHLORO(1,5-CYCLOOCTADIENE)IRIDATE (I) DIMER;IRIDIUM(I) CHLORIDE 1,5-CYCLOOCTADIENE COMPLEX DIMER
  • CAS No.:   12112-67-3
  • Molecular Formula:   C16H24Cl2Ir2
  • Molecular Weight :   671.7
  • Specification :   98%
  • Place of Origin:   China
  • Appearance :   
  • Document :   Download

Description of Chloro(1,5-cyclooctadiene)iridium(I) dimer
Chloro(1,5-cyclooctadiene)iridium(I) dimer Chemical Properties
Melting point  205 °C (dec.)(lit.)
storage temp.  2-8°C
form  Powder
color  red to orange
Water Solubility  insoluble
Safety Information
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
F  10
TSCA  No
HS Code  28439000
Chloro(1,5-cyclooctadiene)iridium(I) dimer Usage And Synthesis
Reactions 1. Precursor to catalysts for the asymmetric hydrogenation of tri- and tetrasubstituted olefins.
2. Precursor to catalyst for enantioselective reduction of imines.
3. Precursor to catalyst for allylic alkylation.
4. Precursor to catalyst for allylic amination and etherification.
5. Precursor to catalyst for the reaction of aroyl chlorides with internal alkynes to produce substituted naphthalenes and anthracenes.
6. Ir-catalyzed addition of acid chlorides to terminal alkynes.
7. Intramolecular hydroamination of unactivated alkenes with secondary alkyl- and arylamines.
8. Enantioselective [2+2] cycloaddition.
9. Silyl-directed, Ir-catalyzed ortho-borylation of arenes.
10. Ir-catalyzed cross-coupling of styrene derivatives with allylic carbonates.
11. Transfer hydrogenative C-C coupling
Chemical Properties red-orange solid
Chloro(1,5-cyclooctadiene)iridium(I) dimer Preparation Products And Raw materials
Raw materials Tetrahydrofuran-->Isopropanol-->Hydrazinium hydroxide-->Hydroquinone-->1,5-Cyclooctadiene-->Iridium(III) chloride hydrate

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