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  • Product Name:   Tris(dibenzylideneacetone)dipalladium-chloroform adduct
  • Synonyms:   TRIS(DIBENZYLIDENEACETONE)(CHLOROFORM)-DI-PALLADIUM(0);TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM(0) CHLOROFORM ADDUCT;TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM CHLOROFORM COMPLEX;DIPALLADIUM(0)TRIS(DIBENZYLIDENEACETONE)-CHLOROFORM ADDUCT;DI-PALLADIUM-TRIS(DIBENZYLIDENEACETONE)CHLOROFORM COMPLEX
  • CAS No.:   52522-40-4
  • Molecular Formula:   C52H43Cl3O3Pd2
  • Molecular Weight :   1035.09502
  • Specification :   98%
  • Place of Origin:   China
  • Appearance :   
  • Document :   Download

Description of Tris(dibenzylideneacetone)dipalladium-chloroform adduct
Tris(dibenzylideneacetone)dipalladium-chloroform adduct Chemical Properties
Melting point  131-135 °C(lit.)
storage temp.  0-6°C
form  Crystalline Powder
color  Purple to black
Water Solubility  Soluble in organic solvents. Insoluble in water.
Sensitive  Air & Moisture Sensitive
InChIKey NLYJPAJWGANOKG-CXKPDERJSA-N
Safety Information
Hazard Codes  Xn,Xi
Risk Statements  22-38-40-48/20/22-36/37/38
Safety Statements  36/37-37/39-26
WGK Germany  3
Tris(dibenzylideneacetone)dipalladium-chloroform adduct Usage And Synthesis
Reaction
  1. Used for Pd-catalyzed asymmetric arylation, vinylation, and Allenylation of tert-cyclobutanols via enantioselective C−C Bond cleavage.
  2. Used for synthesis of chiral chromans through the Pd-catalyzed asymmetric allylic alkylation (AAA).
  3. Catalyst for double N-arylation of primary amines to synthesize multisubstituted carbazoles from 2,2‘- biphenylylene ditriflates.
  4. Paladium catalyst for regio- and enantioselective allylic alkylation of ketones through allyl enol carbonates.
  5. Used for Pd-catalyzed enantioselective C-3 allylation of 3-substituted-1H-indoles using trialkylboranes.
  6. Used for enantioselective construction of spirocyclic oxindolic cyclopentanes by Pd-catalyzed trimethylenemethane-[3+2]-cycloaddition.
  7. Used for Pd-catalyzed insertion of α-diazoesters into vinyl halides to generate α,β-unsaturated γ-amino Esters.
  8. Pd catalyst for decarboxylative asymmetric allylic alkylation of enol carbonates.
  9. Palladium catalyst for asymmetric addition of oxindoles and allenes.
  10. Catalyst for diastereo- and enantioselective formal [3+2]-cycloaddition between substituted vinylcyclopropanes and electron-deficient olefins.
  11. Used for Pd-catalyzed asymmetric decarboxylative cycloaddition of vinylethylene carbonates with Michael sacceptors.
  12. Catalyst for enantioselective [6+4] cycloaddition of vinyl oxetanes with azadienes to access ten-membered heterocycles.
Chemical Properties purple to black crystalline powder
Uses suzuki reaction
Biological Activity N -myristoyltransferase-1 (NMT-1) inhibitor that prevents activation of MAPK, PI 3-K and STAT3 signaling pathways. Exhibits antiproliferative activity against melanoma cells in vitro and in vivo . Also used as a cyclization catalyst.
Tris(dibenzylideneacetone)dipalladium-chloroform adduct Preparation Products And Raw materials
Raw materials Etanol-->Sodium hydroxide-->Methanol-->Diethyl ether-->Dichloromethane-->Toluene-->Chloroform-->Acetone-->Ammonium chloride -->Acetonitrile-->Sodium acetate-->Benzaldehyde-->Palladium chloride-->tert-Butyl methyl ether

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