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  • Product Name:   3-Methylpiperidine
  • Synonyms:   β-Pipecoline, 3-Pipecoline;(R,S)-3-Methyl-piperidine;3-methyl-piperidin;3-pipercoline(beta-);beta-Methylpiperidine
  • CAS No.:   626-56-2
  • Molecular Formula:   C6H13N
  • Molecular Weight :   99.17
  • Specification :   98%
  • Place of Origin:   China
  • Appearance :   
  • Document :   Download

Description of 3-Methylpiperidine



3-Methylpiperidine Chemical Properties


Melting point  -24 °C


Boiling point  125-126 °C763 mm Hg(lit.)


density  0.845 g/mL at 25 °C(lit.)


refractive index  n20/D 1.447(lit.)


Fp  63 °F


storage temp.  Flammables area


Water Solubility  miscible


BRN  79807


CAS DataBase Reference 626-56-2(CAS DataBase Reference)


NIST Chemistry Reference Piperidine, 3-methyl-(626-56-2)


EPA Substance Registry System Piperidine, 3-methyl-(626-56-2)




Safety Information


Hazard Codes  F,Xi


Risk Statements  11-36/37/38


Safety Statements  16-23-33-26-7/9


RIDADR  UN 1993 3/PG 2


WGK Germany  3


TSCA  Yes


HazardClass  3


PackingGroup  II




3-Methylpiperidine Usage And Synthesis


Chemical Properties clear colorless to yellow liquid


General Description A colorless liquid with a characteristic odor. Less dense than water. Flash point less than 141°F. Contact may cause severe irritation to skin, eyes, and mucous membranes. Toxic by ingestion, inhalation and skin absorption.


Air & Water Reactions Highly flammable. Water soluble.


Reactivity Profile 3-METHYLPIPERIDINE neutralizes acids to form salts plus water in exothermic reactions. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Generates flammable gaseous hydrogen in combination with strong reducing agents, such as hydrides.


Health Hazard May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.


Fire Hazard Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.


Purification Methods Purify it via the hydrochloride (m 172o). The hydrobromide has m 162-163o(from iso-PrOH). [Chapman et al. J Chem Soc 1925 1959, Beilstein 20 III/IV 1499, 20/4 V 100.]




3-Methylpiperidine Preparation Products And Raw materials


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